吴华教授团队简介
团队依托江苏省农药学重点实验室和william威廉亚洲官方实验中心平台的有利条件,近年来主要致力于具有光学性质、生物学活性、磁学及优异催化性能的新型有机-无机杂化材料的设计合成与性质研究。团队的主要研究方向有:(1)基于多金属氧酸的有机-无机杂化材料的设计与合成;(2)微米及纳米孔金属-有机晶体材料的合成与性质研究;(3)基于多金属氧酸盐的农药分子设计合成与抗菌活性研究。目前团队在以上研究方向的基础上,对合成材料进行大量有机物污染和重金属吸附与降解研究,力求将合成的材料用于污染废水的降解处理。部分研究成果发表在Journal of the American Chemical Society., Chemical Communications., Crystal Growth & Design., CrystEngComm等期刊上。
近年承担的重大、重点课题
1. “大环多胺-多酸”主客体自组装体系的构建与催化性能研究(国家自然基金面上项目,时间2014.01-2015.12,项目负责人吴华)
2. 多氮唑类农药配体修饰的多酸配合物的合成、结构及抗菌活性研究(中央高校基本科研业务经费,时间2013.01-2015.12,项目负责人吴华)
3. 新型“含氮大环-多酸”配合物的构建及催化性能研究(江苏省科技厅面上项目,时间2013.7-2016.6 ,主持人吴华)
近年主要代表作有:
1. Two CdII -containing coordination polymers based on trinuclear and dodecanuclear clusters. Inorganic Chemistry Communications, 2016, 70, 90–94.
Yuehong Tao, Xueqin Zhou, Zikai Wang, Ying Shi, Yao Guo, Hua Wu
2. Diverse topologies of seven d10 coordination polymers constructed from a long ligand and different carboxylates. CrystEngComm, 2014, 16, 992–1000.
Hua Wu, Xiao-Li Lü, Chun-Long Yang, Chang-Xun Dong, Mei-Sheng Wu.
3. Three coordination polymers based on different carboxylates, metals and a tri(4-imidazolylphenyl)amine ligand. Journal of Molecular Structure, 2015, 1086, 276–281.
Hua Wu, Chenjie Shi, Yanqing Zhao, Yutong Jiang, Yuehong Tao.
4. A novel three-dimensional AgI coordination polymer based on mixed naphthalene-1,5-disulfonate and aminoacetate ligands. Acta Cryst. 2013, C69.
5. pH-Controlled Assembly of Two Unusual Entangled Motifs Based on a Tridentate Ligand and Octamolybdate Clusters: 1D + 1D→3D Poly-Pseudorotaxane and 2D→2D→3D Polycatenation. Crystal Growth & Design., 2012, 12, 2272–2276.
Hua Wu, Jin Yang, Ying-Ying Liu, and Jian-Fang Ma.
6. An Exceptional 54-Fold Interpenetrated Coordination Polymer with 103-srs Network Topology. Journal of the American Chemical Society., 2011, 133, 11406–11409.
Hua Wu, Jin Yang, Zhong-Min Su, Stuart R. Batten, and Jian-Fang Ma.
7. An unprecedented 2D - 3D metal–organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand. Chemical Communications., 2011, 47, 1818–1820.
Hua Wu, Hai-Yan Liu,Ying-Ying Liu,Jin Yang,Bo Liu,and Jian-Fang Ma.
8. Series of Coordination Polymers Based on Different Carboxylates and a Tri(4-imidazolylphenyl)amine Ligand: Entangled Structures and Photoluminescence. Crystal Growth & Design., 2011, 11, 2317–2324.
Hua Wu, Hai-Yan Liu, Jin Yang, Bo Liu, Jian-Fang Ma, and Yun-Yu Liu.